Product/Chemical Name: Citric Acid, anhydrous
Chemical Formula: C6H8O7
CAS Number: 77-29-9
Other Designations: 2-Hydroxy-1,2,3-tricarboxylic acid, B-hydroxytricarballyic acid
Derivation: A tricarboxylic acid derived by mycological fermentation using crude sugars such as molasses with strains of Aspergillus niger or yeast (Candida lypolytica). It may also be extracted from citrus fruit (lemon juice contains 5 to 8% citric acid) and pineapple waste.
General Use: Used as a food additive for many different applications including; flavor enhancer, acidifying and buffering agent, and antioxidant; in the manufacture of alkyd resins and citric acid salts, in pharmaceuticals for preparation of effervescent antacid powders; for cleaning and polishing metals, removing sulfur dioxide from smelter waste gases; a sequestering agent to remove trace metals, mordant to brighten colors, in electroplating, special inks, and analytical chemistry. Used in medicine as a blood anticoagulant.
Emergency Telephone: 1-800-424-9300 (Chemtrec)
Section 2 - Composition / Information on Ingredients
Trace Impurities:
| |
OSHA PEL |
ACGIH TLV |
NIOSH REL |
NIOSH |
Ingredient |
TWA |
STEL |
TWA |
STEL |
TWA |
STEL |
IDLH |
Citric Acid, anhydrous |
15 mg/m3 |
none estab. |
10 mg/m3 |
none estab. |
none estab. |
none estab. |
none estab. |
Section 3 - Hazards Identification
Emergency Overview
HMIS |
H
F
R |
2
1
0 |
PPE†
†Sec. 8 |
Warning! Causes respiratory tract irritation. Causes skin irritation. Causes digestive tract irritation. May cause severe eye irritation and possible injury.
Potential Health Effects
Primary Entry Routes: Inhalation, ingestion, skin and eye contact.
Target Organs: Eyes, skin, respiratory tract.
Acute Effects
Inhalation: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Citric acid decreases iron and calcium absorption.
Eye: Contact with eyes may cause severe irritation, and possible eye burns.
Skin: May cause skin irritation.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Citric acid decreases iron and calcium absorption.
Carcinogenicity: IARC, NTP, and OSHA do not list citric acid as a carcinogen.
Medical Conditions Aggravated by Long-Term Exposure:
Chronic Effects: Chronic or heavy acute ingestion may cause tooth enamel erosion.
Section 4 - First Aid Measures
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately.
Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.
After first aid, get appropriate in-plant, paramedic, or community medical support.
Note to Physicians: Treat symptomatically and supportively.
Section 5 - Fire-Fighting Measures
Flash Point: ?? °F (?? °C)..................
Flash Point Method: CC?, OC?, COC?
Burning Rate: ..................................
Autoignition Temperature: ?? °F (?? °C)
LEL: ??% v/v
UEL: ??% v/v
Flammability Classification:
Extinguishing Media:
Unusual Fire or Explosion Hazards:
Hazardous Combustion Products:
Fire-Fighting Instructions: Do not release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode.
Section 6 - Accidental Release Measures.
Spill /Leak Procedures:
Small Spills:
Large Spills
Containment: For large spills, dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways.
Cleanup:
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions:
Storage Requirements:
Section 8 - Exposure Controls / Personal Protection
Engineering Controls:
Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec. 2). Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source.
Administrative Controls:
Respiratory Protection: Seek professional advice prior to respirator selection and use. Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, wear a MSHA/NIOSH-approved respirator. Select respirator based on its suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of sufficient oxygen. For emergency or nonroutine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. Warning! Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If respirators are used, OSHA requires a written respiratory protection program that includes at least: medical certification, training, fit-testing, periodic environmental monitoring, maintenance, inspection, cleaning, and convenient, sanitary storage areas.
Protective Clothing/Equipment: Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations (29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.
Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this material from your shoes and clean personal protective equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics.
Section 9 - Physical and Chemical Properties
Physical State: solid
Appearance and Odor: white crystals/odorless
Odor Threshold:
Vapor Pressure: Not applicable.
Vapor Density (Air=1): Not applicable.
Formula Weight: 192.12
Bulk Density: 56.2 lb/ft3
Specific Gravity (H2O=1, at 4 °C): 1.7
pH (0.1 N solution): 2.2 |
Water Solubility: Very soluble
Other Solubilities: ether 2.17, chloroform 0.007, amyl alcohol 15.43, amyl acetate 5.98, ethyl acetate 5.28. At 19 °C; soluble in methanol 197 and propanol 62.8. It is insoluble in benzene.
Boiling Point: Decomposes
Freezing/Melting Point: (153 °C)
Viscosity (50% aqueous soln.): 6.5 cP at 77 °F (25 °C)
Refractive Index: 1.493 to 1.509 at 68 °F (20 °C) |
Section 10 - Stability and Reactivity
Stability: Citric acid is stable at room temperature in closed containers under normal storage and handling conditions. Anhydrous citric acid readily absorbs moisture from air.
Polymerization: Hazardous polymerization cannot occur.
Chemical Incompatibilities: Include potassium tartrate, alkali and alkaline earth carbonates and bicarbonates, acetates, sulfites, and metal nitrates (potentially explosive reaction). Citric acid corrodes copper, zinc, aluminum and their alloys.
Conditions to Avoid: Dispersing powder in the air, contact with incompatibles, and exposure to heat and ignition sources.
Hazardous Decomposition Products: Thermal oxidative decomposition of citric acid can produce acrid, irritating smoke and carbon monoxide, carbon dioxide.
Section 11- Toxicological Information
Rabbit, eye: 750 mg/24 hr caused severe irritation.
Rabbit, skin: 500 mg/24 hr caused moderate irritation. |
Acute Inhalation Effects:
Human, inhalation, TCLo: ?? ppm
Acute Oral Effects:
Rat, oral, LD50: 6730 mg/kg
Chronic Effects:
Carcinogenicity:
Mutagenicity: No data available.
Teratogenicity: No data available. |
- See NIOSH, RTECS (GE7350000), for additional toxicity data.
Section 12 - Ecological Information
Ecotoxicity: Acute aquatic effects: 96-hour LC50; Fathead minnow: GT 1000 mg/L. 96-hour LC50; Water flea: GT 1000 mg/L. 48-hour LC50; Golden orfe (minnow): 760 mg/L.
Environmental Fate: This chemical is expected to be readily biodegradable and is not likely to bioconcentrate.
Environmental Degradation:
Soil Absorption/Mobility:
Section 13 - Disposal Considerations
Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and local regulations.
Section 14 - Transport Information
DOT Transportation Data (49 CFR 172.101): NOT REGULATED
Shipping Name:
Shipping Symbols:
Hazard Class:
ID No.:
Packing Group:
Label:
Special Provisions (172.102): |
Packaging Authorizations
a) Exceptions:
b) Non-bulk Packaging:
c) Bulk Packaging: |
Quantity Limitations
a) Passenger, Aircraft, or Railcar:
b) Cargo Aircraft Only:
Vessel Stowage Requirements
a) Vessel Stowage:
b) Other: |
Section 15 - Regulatory Information
TSCA
CAS# 77-92-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 77-92-9: acute.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 77-92-9 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases: Phrases:
Section 16 - Other Information
Disclaimer: All information, recommendations and suggestions appearing herein are based upon sources believed to be reliable: However, it is the user’s responsibility to determine the safety, toxicity and suitability for its own use of this product. Federated Mills, Inc. DOES NOT ASSUME ANY LIABILITY ARISING OUT OF THE USE BY OTHERS OF THIS PRODUCT